The reaction of non-phenolic B-O-4 type lignin in alkaline media

By: Call Number: AIT Thesis no.PP-13-03 Contributor(s): Material type: SeriesSeries: Asian Institute of Technology. Thesis ; no. PP-13-03Publication details: Pathum Thani, Thailand : Asian Institute of Technology, 2013Description: 1 online resource (60 leaves) : illSubject(s): Online resources: Dissertation note: Thesis (M. Eng.) - Asian Institute of Technology, 2013 Summary: In this research, the lignin reactivity during alkaline delignification was quantitatively investigated focusing on the effect of the structural differences between syringyl and guaiacyl aromatics nuclei as well as various alkaline conditions on theÝ-O-4 bond cleavage rate.Moreover, the lignin compounds with 2-carbon side chains were studied to avoid the complex kinetics caused by the propanol diastereomers which hydrolyze at different rates and the Ü{u2013}and Þ{u2013}hydroxyls both participating in the displacement reaction.The presence of a syringyl nucleus, increasing of the reaction temperature as well as higher alkaline concentration influenced the increasing of the reaction rate.
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20-AIT Publication Asian Institute of Technology Library AIT Publications AIT Thesis no.PP-13-03 (Browse shelf(Opens below)) 2 Available 30050120668552
20-AIT Publication Asian Institute of Technology Library AIT Publications AIT Thesis no.PP-13-03 (Browse shelf(Opens below)) 1 Available 30050120668537
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14-General Book Asian Institute of Technology Library AIT Thesis no.PP-13-03 (Browse shelf(Opens below)) 4 Available 30050120902738

A thesis submitted in partial fulfillment of the requirements for the Degree of Master of Engineering in Pulp and Paper Technology

Thesis (M. Eng.) - Asian Institute of Technology, 2013

In this research, the lignin reactivity during alkaline delignification was quantitatively investigated focusing on the effect of the structural differences between syringyl and guaiacyl aromatics nuclei as well as various alkaline conditions on theÝ-O-4 bond cleavage rate.Moreover, the lignin compounds with 2-carbon side chains were studied to avoid the complex kinetics caused by the propanol diastereomers which hydrolyze at different rates and the Ü{u2013}and Þ{u2013}hydroxyls both participating in the displacement reaction.The presence of a syringyl nucleus, increasing of the reaction temperature as well as higher alkaline concentration influenced the increasing of the reaction rate.

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