Copper and lead adsorption in Boraphet Lake sediment and potential removal using physico-chemical treatments (Record no. 23423)

MARC details
000 -LEADER
fixed length control field 06415nam a2200469 a 4500
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20260818085158.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 140619s2012 th ad ||| |000 0 eng d
035 ## - SYSTEM CONTROL NUMBER
System control number .b12134338
099 #9 - LOCAL FREE-TEXT CALL NUMBER (OCLC)
Classification number AIT Thesis no.EV-12-20
100 0# - MAIN ENTRY--PERSONAL NAME
Personal name Thuangsit Denpetkul
245 10 - TITLE STATEMENT
Title Copper and lead adsorption in Boraphet Lake sediment and potential removal using physico-chemical treatments
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Pathum Thani :
Name of publisher, distributor, etc. Asian Institute of Technology,
Date of publication, distribution, etc. 2012
300 ## - PHYSICAL DESCRIPTION
Extent 132 p. :
Other physical details ill., maps, charts +
Accompanying material 1 online resource
490 1# - SERIES STATEMENT
Series statement Thesis ;
Volume/sequential designation no. EV-12-20
500 ## - GENERAL NOTE
General note A thesis submitted in partial fulfillment of the requirements for the degree of Master of Engineering in Environmental Engineering and Management Inter - University Program on Environmental Toxicology, Technology and Management
502 ## - DISSERTATION NOTE
Dissertation note Thesis (M.Eng.) - Asian Institute of Technology - Chulabhorn Research Institute - Mahidol University, 2012
520 ## - SUMMARY, ETC.
Summary, etc. Bung Boraphet is the largest fresh water lake that located at Nakornsawan, the lower Northern of Thailand and covered area more than 300 km² in flooding season. It receives the water from 2 rivers before unite into Chao Praya river. This Lake has been considered as a great important natural resource and biodiversity, because many living things including over 30,000 people gain a lot of profits for a longtime. However, since 2009, it has been reported to be the contaminated area with heavy metals, especially Copper and Lead. Bioaccumulation of heavy metals by biota in surface water and by plants and animals in terrestrial environments can adversely affect humans. Most Heavy metals can be dispersed in sediment and water. In order to understand the bioavailability and its mobilization, more attention should be paid on the characteristic of sediment and practical treatment method. In this study, sediments were collected from 7 sites around Bung Boraphet Lake in December 2011. This study was divided into 3 phases and conducted in batch reactors. Firstly, to evaluate the amount of Cu (II) and Pb (II) in each environmental media, characterization of sediment and water was investigated. Secondly, the adsorption capacity and kinetics of Cu (II) and Pb (II) onto sediment was performed. Finally, sediment samples were spike with 500 mg/l of Cu(II) and 800 mg/l of Pb (II) and incubated for one and half month for simulating highly contaminated scenario, sequently, the capacity and treatment efficiency three absorbents; Activated carbon, Bentonite and compost were examined. The result reveal that pH of sediment is about 5.5-6 indicated the acidic condition and has a significant background Copper and Lead 47.3±3.3 and. 17.63±1.04 mg/L, respectively. It suggests that Lead had major trend of over standard which require remediation. Moreover, from fractionation study, the most common fraction of Copper was residual, with 30.54 g/kg (71.39%), whereas Lead was Fe-Mn oxide bond, with 10.85 g/kg (31.15%). This finding indicated that Lead has a high potential risk over Copper, because it highly existed in the mobile and exchangeable form. Based on study of adsorption kinetics of sediment, it demonstrated that single metal both Copper or Lead was rapidly adsorbed onto sediment more than its binary metal condition. It may due to the effect of ionic strength and competition between Copper and Lead for the sorption site. Furthermore, the behavior of Lead and Copper adsorption in both of single metals and binary metals were more associated with pseudo-second order model with high R2. The calculated capacity at equilibrium (qe) corresponded to the experimental values with low %{uF044}q. However, it revealed that qe of both binary system were fairly lower than single metal ion system. This may be an evidence of competition between metals on adsorbent. Additionally, Isotherm study exhibited that it is better fitted with the Langmuir isotherm for both Cu(ll) and Pb(II) and the maximum capacity for this sediment were Qm, Cu= 3690 mg/kg and Qm,pb= 3206.2 mg/kg, respectively. In contrast, the study of kinetics and isotherm of Activated carbon and Bentonite revealed that Freundlich isotherm could well explain the adsorption mechanism of both adsorbents and also provide its Freundlich constant (Kf) roughly 0.87-1.82 mg/g and 0.007-0.008 mg/g for Activated carbon and Bentonite, respectively. Finally, the removal efficiency of heavy metals focusing on Copper and Lead in each adsorbents could be put into order from high to low; Activated carbon > Compost >Bentonite.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Water
General subdivision Lead content
Geographic subdivision Thailand
-- Boraphet Lake
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Sewage
General subdivision Purification
-- Chemical treatment
Geographic subdivision Thailand
-- Boraphet Lake
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Water
General subdivision Copper content
Geographic subdivision Thailand
-- Boraphet Lake
700 0# - ADDED ENTRY--PERSONAL NAME
Personal name Preeda Pakpian,
Relator term Chairperson
700 0# - ADDED ENTRY--PERSONAL NAME
Personal name Jutamaad Satayavivad,
Relator term Co-chairperson
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Visvanathan, C.,
Relator term Examination Committee
710 2# - ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Chulabhorn Research Institute,
Relator term Scholarship donor
710 2# - ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Mahidol University,
Relator term Scholarship donor
710 2# - ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Royal Thai Government Fellowship,
Relator term Scholarship donor
810 2# - SERIES ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Asian Institute of Technology.
Title of a work Thesis ;
Volume/sequential designation no. EV-12-20
856 ## - ELECTRONIC LOCATION AND ACCESS
Materials specified Full-Text
Uniform Resource Identifier <a href="http://203.159.5.9/ait-thesis/detail.php?q=B02528">http://203.159.5.9/ait-thesis/detail.php?q=B02528</a>
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Cataloger's initials, CIN (RLIN) 140619
First date, FD (RLIN) m
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Koha item type 20-AIT Publication
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      Available for Loans Asian Institute of Technology Library Asian Institute of Technology Library AIT Publications 18/08/2026 50.00   AIT Thesis no.EV-12-20 30050120735641 18/08/2026 1 18/08/2026 20-AIT Publication
      Available for Loans Asian Institute of Technology Library Asian Institute of Technology Library AIT Publications 18/08/2026 50.00   AIT Thesis no.EV-12-20 30050120735658 18/08/2026 2 18/08/2026 20-AIT Publication
      Available for Loans Asian Institute of Technology Library Asian Institute of Technology Library Archives 18/08/2026     AIT Thesis no.EV-12-20 30050160047865 18/08/2026   18/08/2026 40-Archives
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