Effects of organic acids and salt concentrations on chitosan membrane properties (Record no. 35259)

MARC details
000 -LEADER
fixed length control field 04899nas|a2200409 i 4500
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20260818095304.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 030418s2002 th u m rtt 0| a1eng d
035 ## - SYSTEM CONTROL NUMBER
System control number .b11880806
099 #9 - LOCAL FREE-TEXT CALL NUMBER (OCLC)
Classification number AIT Thesis no. BP-02-11
100 0# - MAIN ENTRY--PERSONAL NAME
Personal name Nguyen Thi Quy
245 10 - TITLE STATEMENT
Title Effects of organic acids and salt concentrations on chitosan membrane properties
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Bangkok :
Name of publisher, distributor, etc. Asian Institute of Technology,
Date of publication, distribution, etc. 2002
300 ## - PHYSICAL DESCRIPTION
Extent 71 leaves :
Other physical details ill.
490 1# - SERIES STATEMENT
Series statement Thesis ;
Volume/sequential designation no. BP-02-11
500 ## - GENERAL NOTE
General note A thesis submitted in partial fulfillment of the requirements for the degree of Master of Science, School of Environment, Resources and Development
502 ## - DISSERTATION NOTE
Dissertation note Thesis (M.Sc.) - Asian Institute of Technology, 2002
520 ## - SUMMARY, ETC.
Summary, etc. The membrane prope1iies of two chitosan samples were examined by using six different organic solvents (formic, acetic, propionic, glycolic, lactic and citric acid) as dissolving solvents. Their degrees of deacetylation (DD) are 70% (termed low DD) and 95% (termed high DD). Both chitosans are having a weight average molecular weight of 0.8 M Dalton. The physico-chemical properties of the membranes prepared from these organic acids were characterized. Both degree of deacetylation and the organic acids used affected the membranes properties. The X-ray diffraction patterns indicated that high DD membranes possess three major peaks at 10°, 15° and 20° (28) whereas low DD membranes have their sole peak at 10° (28). High DD membrane prepared from formic, glycolic and citric acids are having relatively lower crystallinity than membranes from other solvents. It is observed that the tensile strength and elongation-at-break increases as the DD increased; however, the swelling index, biodegradability through lysozyme activity and permeability of membranes with sodium salicylate reduced. Propionic acid improved significantly the tensile strength in both low and high DD membranes but gave the lowest pe1meation rate in case of high DD membrane, while glycolic and formic acid resulted in the lowest tensile strength but highest permeability among high DD membranes. Both low and high DD chitosan membrane produced from lactic acid were most resistant to lysozymic degradation. Jn contrast, the low DD citric membrane has been most susceptible to lysozyme. Effect of sodium chloride concentration on preparing chitosan membrane properties was examined. The increase of sodium chloride concentration in the tested range of 0-0.3% reduces crystallinity of the high DD membranes but increases peak intensity of low DD membranes. The increase of sodium chloride concentration increases the swelling index of chitosan membranes. For low DD membrane, sodium chloride in the range of 0 to 0.1 % improved significantly tensile strength but no significant effect on high DD membrane has been observed. There is a sharp reduction in the tensile strength when sodium chloride concentration is increased to 0.3%. This effect ha been more significant in the high DD membranes. Elongation-at-break reduces as sodium chloride concentration increased. Salt concentration is also observed to have an effect on biodegradability and permeability of membrane. Sodium chloride at 0.05% leads to fastest degradation of low DD membrane but no significant effect on high DD membrane. Beyond the other salt concentrations were resistant to lysozyme for both low and high DD membranes. Permeability was increased when low DD membrane was added with 0.05% NaCl; it reduced when the membrane was treated with 0.3% NaCl. The permeability characteristics of high DD membranes have been reversed to that of low DD membranes. Treatments with 0.05 and 0.1 % salt reduce the permeability, whereas it was increased for high DD membrane if 0.3% salt was introduced. This result has been consistent with the X-ray diffractograms of membranes with salt.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Chitosan
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Organic acids
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Stevens, Willem Frans,
Relator term Chairperson
700 0# - ADDED ENTRY--PERSONAL NAME
Personal name Suwalee Chandrkrachang,
Relator term Examination committee
700 0# - ADDED ENTRY--PERSONAL NAME
Personal name Suwabun Chirachanchai,
Relator term Examination committee
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Trankler, Josef,
Relator term Examination Committee
710 2# - ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element New Zealand
Relator term Scholarship donor
810 2# - SERIES ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Asian Institute of Technology.
Title of a work Thesis ;
Volume/sequential designation no. BP-02-11
856 ## - ELECTRONIC LOCATION AND ACCESS
Materials specified Full-Text
Uniform Resource Identifier <a href="http://203.159.5.9/ait-thesis/detail.php?q=B07383">http://203.159.5.9/ait-thesis/detail.php?q=B07383</a>
907 ## - LOCAL DATA ELEMENT G, LDG (RLIN)
a .b11880806
b mnait
c u
902 ## - LOCAL DATA ELEMENT B, LDB (RLIN)
a 240403
998 ## - LOCAL CONTROL INFORMATION (RLIN)
Operator's initials, OID (RLIN) 0
Cataloger's initials, CIN (RLIN) 030418
First date, FD (RLIN) m
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-- u
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945 ## - LOCAL PROCESSING INFORMATION (OCLC)
l mnait
945 ## - LOCAL PROCESSING INFORMATION (OCLC)
l mnarc
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type 22-AIT Thesis (Replacement)
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type 40-Archives
909 ## - LOCAL ITEMS USED
Barcode Barcode : 30050120682983
CREATED CREATED : 2013-06-09
RECORD Id RECORD # : i12739881
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909 ## - LOCAL ITEMS USED
Barcode Barcode : 30050120350664
CREATED CREATED : 2016-10-06
RECORD Id RECORD # : i13030097
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LCHKIN LCHKIN : -
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Holdings
Withdrawn status Lost status Damaged status Not for loan Home library Current library Shelving location Date acquired Cost, normal purchase price Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
      Available for Loans Asian Institute of Technology Library Asian Institute of Technology Library AIT Publications 18/08/2026 50.00   AIT Thesis no. BP-02-11 30050120682983 18/08/2026 3 18/08/2026 22-AIT Thesis (Replacement)
      Available for Loans Asian Institute of Technology Library Asian Institute of Technology Library Archives 18/08/2026     AIT Thesis no. BP-02-11 30050120350664 18/08/2026   18/08/2026 40-Archives
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