Anaerobic degradation of chlorophenols (Record no. 4348)

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005 - DATE AND TIME OF LATEST TRANSACTION
control field 20260817162225.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 170399s1993 th uzm rtt 00| a1eng d
035 ## - SYSTEM CONTROL NUMBER
System control number .b10078903
099 #9 - LOCAL FREE-TEXT CALL NUMBER (OCLC)
Classification number AIT Thesis no.EV-93-06
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Cheema, Muhammad Javaid
245 10 - TITLE STATEMENT
Title Anaerobic degradation of chlorophenols
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Bangkok :
Name of publisher, distributor, etc. Asian Institute of Technology,
Date of publication, distribution, etc. 1993
300 ## - PHYSICAL DESCRIPTION
Extent 133 leaves +
Accompanying material 1 online resource
490 1# - SERIES STATEMENT
Series statement Thesis ;
Volume/sequential designation no. EV-93-06
500 ## - GENERAL NOTE
General note A thesis submitted in partial fulfillment of the requirements for the Degree of Master of Engineering
502 ## - DISSERTATION NOTE
Dissertation note Thesis (M.Eng.) - Asian Institute of Technology, 1993
520 ## - SUMMARY, ETC.
Summary, etc. Two lab scale anaerobic filters (AFs) were operated to investigate the potential of AFs for the treatment of chlorophenolic wastewater. With AF1, a substrate loading rate of 150 mg/l/day (2-MCP) was possible and with AF2, 20 mg/I/day (2,4,6-TCP) was completely dechlorinated, but major intermediate degradation product, 4-MCP was virtually persistent. About 91 % of total influent TCP organic carbon was converted to 4-MCP. And AF2, community did not have species that could degrade 4-MCP. TCP follow pathways i. e, TCP-> 2,4-DCP--> 4-MCP and 2,4-DCP --> 2-MCP -->phenol. Very less concentration of 2- MCP could be detected in the reactor effluent. The TOC reduction was about 98 % , with mass balance 82 % , and 18 % of the carbon was being utilized for biomass production. In both AFs effluent pH increased (6.8 to 7.9),due to consumption of hydrogen ions, while _reduction of sulfate to H2S and Hs·. SEM study of reactor sludge, fed with 2-MCP showed the dominancy of Methanothrix and Desulfovibrio spp. Concentration of maximum influent possible chloride ions and actual effluent concentration were same, which confirmed that the chlorophenols reduction was due to the biodegradation mechanism, through reductive dechlorination but not due to volatilization, or some abiotic mechanism. Addition of molybdate (20 mM), a specific inhibitor of Sulfate Reducing Bacteria (SRB) completely inhibited the dechlorination of 2-MCP and ring cleavage of phenol did not occur also. But degradation of 2-MCP also completely stopped in the MPBs inhibited enrichment with the addition of 0.5 mM chloroform. So it can be inferred that 2-MCP degradation was not only due to SRBs, but due to syntrophic association with MPBs. Relative disappearance of monochlorophenols isomers, in the TCP acclimated community, was in this order: ortho > meta >para, demonstrated that rate of dechlorination of different monochlorophenol isomers was related to position of chlorine substituent on the benzene ring. Presence of glucose as cosubstrate stimulated, dechlorination of chlorophenols.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Sewage
General subdivision Purification
-- Phenol removal
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Tanaka, Shuzo,
Relator term Chairperson
700 0# - ADDED ENTRY--PERSONAL NAME
Personal name Chongrak Polprasert,
Relator term Examination Committee
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Visvanathan, C.,
Relator term Examination Committee
710 2# - ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Government of Denmark,
Relator term Scholarship donor
810 2# - SERIES ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Asian Institute of Technology.
Title of a work Thesis ;
Volume/sequential designation no. EV-93-06
856 ## - ELECTRONIC LOCATION AND ACCESS
Materials specified Full-Text
Uniform Resource Identifier <a href="http://203.159.5.9/ait-thesis/detail.php?q=B16207">http://203.159.5.9/ait-thesis/detail.php?q=B16207</a>
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Operator's initials, OID (RLIN) 2
Cataloger's initials, CIN (RLIN) 951012
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Koha item type 22-AIT Thesis (Replacement)
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Koha item type 40-Archives
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CREATED CREATED : 2016-11-05
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