Analysis of a hydrogenation/dehydrogenation system to upgrade heat (Record no. 4561)

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005 - DATE AND TIME OF LATEST TRANSACTION
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008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 290200s1999 th uu m rtt 00| a1eng d
035 ## - SYSTEM CONTROL NUMBER
System control number .b11777655
099 #9 - LOCAL FREE-TEXT CALL NUMBER (OCLC)
Classification number AIT Thesis no.ET-99-35
100 0# - MAIN ENTRY--PERSONAL NAME
Personal name Walaiporn Mooksuwan
245 10 - TITLE STATEMENT
Title Analysis of a hydrogenation/dehydrogenation system to upgrade heat
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Bangkok :
Name of publisher, distributor, etc. Asian Institute of Technology,
Date of publication, distribution, etc. 1999
300 ## - PHYSICAL DESCRIPTION
Extent 116 leaves
490 1# - SERIES STATEMENT
Series statement Thesis ;
Volume/sequential designation no. ET-99-35
500 ## - GENERAL NOTE
General note A thesis submitted in partial fulfillment of the requirements for the degree of Master of Science, School of Environment, Resources and Development
502 ## - DISSERTATION NOTE
Dissertation note Thesis (M.Sc.) - Asian Institute of Technology, 1999
520 ## - SUMMARY, ETC.
Summary, etc. Low-temperature thermal energy can be upgraded to a higher temperature thermal energy by using a heat pump. Among the heat pumps proposed, a 2- Propanol/ Acetone/Hydrogen chemical heat pump is a promising one. This research was aimed to study experimentally the performance of this system using a catalyst that has not been studied earlier. Model for estimating the reaction conversion and theoretical heat energy associated with the reaction has been developed. The results of the simulation have been compared with the literature and the experimental studies. Experiments on 2-propanol dehydrogenation were conducted between the temperature range of 60 °C to 80 °C with a 10 wt% Ru-Pt/ activated C suspended in liquid 2-propanol to study the influences of reaction temperature, catalyst concentration and acetone concentration in liquid reactant on the performance of 2-propanol dehydrogenation. The maximum initial reaction rate 54 mmole/h-g was obtained at reaction temperature 75°C to 80°C with 400 mg catalyst suspended in 300 ml of 2-propanol (1.3 g/l). The maximum heat utilization of 4.5 % was obtained when oil bath temperature was 100°C and 1.3 g/l of catalyst concentration. This is, however, low when compared to the heat utilization factor of a falling film reactor. Experiments on acetone hydrogenation were conducted at the catalyst bed temperature range of 110 °C to 150 °C with 10 wt% Ni-Cu/y-Ah03 suspended the U-tube reactor to find the influences of reaction temperature, catalyst weight and flow rate of hydrogen and acetone on the performance of this reaction. The maximum acetone conversion of 25% was obtained at inlet temperature of 120°C with 0.5651 gm catalyst (the catalyst bed temperature of 150 °C) and hydrogen and acetone flow rate of 0.0153 mole/min and 0.0025 mole/min. For different catalyst bed temperature, the conversion of acetone obtained at hydrogen-acetone (H/A) mole ratio of 4 to 10 seems to be constant, but it tends to decrease at higher H/ A mole ratio (more than 9). A study of a combined hydrogenation - dehydrogenation system has been done based on data obtained from the experimental studies and the heat released at the exothermic reactor for various inlet (endothermic) conditions, the influence of catalyst quantities, etc have been studied.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Heat pumps
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Kumar, Sivanappan,
Relator term Chairperson
700 0# - ADDED ENTRY--PERSONAL NAME
Personal name Surapong Chiraratananon,
Relator term Examination Committee
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Pham, Hoang Luong,
Relator term Examination committee
710 2# - ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Government of France,
Relator term Scholarship donor
810 2# - SERIES ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Asian Institute of Technology.
Title of a work Thesis ;
Volume/sequential designation no. ET-99-35
856 ## - ELECTRONIC LOCATION AND ACCESS
Materials specified Full-Text
Uniform Resource Identifier <a href="http://203.159.5.9/ait-thesis/detail.php?q=B12033">http://203.159.5.9/ait-thesis/detail.php?q=B12033</a>
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998 ## - LOCAL CONTROL INFORMATION (RLIN)
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Cataloger's initials, CIN (RLIN) 000229
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942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type 22-AIT Thesis (Replacement)
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type 40-Archives
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      Available for Loans Asian Institute of Technology Library Asian Institute of Technology Library AIT Publications 17/08/2026 50.00   AIT Thesis no.ET-99-35 30050120731814 17/08/2026 3 17/08/2026 22-AIT Thesis (Replacement)
      Available for Loans Asian Institute of Technology Library Asian Institute of Technology Library Archives 17/08/2026     AIT Thesis no.ET-99-35 30050120365324 17/08/2026   17/08/2026 40-Archives
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