Paraquat adsorption and distribution in soils of Yom River Basin (Record no. 85524)

MARC details
000 -LEADER
fixed length control field 05528nas|a2200433 a 4500
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20260818171229.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 060702s2005 th uu|m rtt 0| a1eng d
035 ## - SYSTEM CONTROL NUMBER
System control number .b11990211
099 #9 - LOCAL FREE-TEXT CALL NUMBER (OCLC)
Classification number AIT Diss. no.EV-05-1
100 0# - MAIN ENTRY--PERSONAL NAME
Personal name Wapakorn Amondham
245 10 - TITLE STATEMENT
Title Paraquat adsorption and distribution in soils of Yom River Basin
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Pathum Thani, Thailand :
Name of publisher, distributor, etc. Asian Institute of Technology,
Date of publication, distribution, etc. 2005
300 ## - PHYSICAL DESCRIPTION
Extent 130 p. :
Other physical details ill.
490 1# - SERIES STATEMENT
Series statement Dissertation ;
Volume/sequential designation no. EV-05-1
500 ## - GENERAL NOTE
General note A dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Technical Science
502 ## - DISSERTATION NOTE
Dissertation note Thesis (Ph.D.) - Asian Institute of Technology, 2005
520 ## - SUMMARY, ETC.
Summary, etc. Environmental behavior of paraquat in representative tropical soils of Yom River basin, Thailand was investigated. The behaviors in each type of soils include adsorption, dissipation, speciation and remobilization were evaluated using both laboratory and field experiment techniques. Adsorption of paraquat was investigated in the representative eight soil samples from the study area using batch equilibration techniques. The results indicated that adsorption depended on soil chemical characteristics, such as exchangeable basic cations and iron content. Multiple regression analysis indicated significant contribution of exchangeable calcium percentage (ECP), total iron content (TFe) and exchangeable sodium percentage (ESP) to paraquat sorption (Q) at low paraquat concentration level (400 mg paraquat kg^-1 ). The ESP and TFe were significant at all concentration levels studied, while ESP was significant only at low level of paraquat adsorption. Adsorption characteristics of paraquat were thoroughly examined in two soils (Soil#1 and Soil#6) which represent clay and sandy loam texture of soil. It was found that adsorption of paraquat was followed Freundlich model and exhibited nonlinear sorption curve with 1/n value less than 1. Paraquat adsorption was higher as expected in clay soil (Soil#1) than sandy loam (Soil#6) soil with the adsorption coefficient (Kf) value of 787 and 18, respectively. Paraquat desorption using 0.01 M CaCl2 was found at very small amount which were 1.92 - 2.36% and 11.72 - 17.95% in Soil#1 and Soil#6, respectively, this indicated hysteresis effect or desorption resistance even in sandy loam soil. Paraquat sorption on soils was characterized by a rapid initial step followed by much slower step. The time dependence of paraquat adsorption was fit to Elovich kinetic model indicated a rate:.. limiting of diffusion process. Rate of sorption in Soil#6 was exceedingly slower than Soil#1. Speciation of paraquat in 300 mg kg-1 spiked sample of Soil#l was identified by sequential extraction technique. Paraquat in a mobile fraction as water soluble and exchangeable fraction were not found in the studied sample. Major fraction of Paraquat was accumulated in the lattice of clay mineral (84.3%) which was the non-mobilized fraction. The minor fraction was organic bound which mobilizable in long-term (15.6%). The readily mobilizable which was oxide and carbonated bound was unimportant in the experiment with the amount less than 0.1 % of total fractions. Paraquat mobility and dissipation studies were conducted using both field and laboratory soil column experiments. Clay soil showed low mobility of paraquat with accumulation occurred mostly in the surface (0-5 cm) layer under field conditions and in the 0-1 cm layer in a laboratory soil column experiment. Dissipation of paraquat in soil was faster under field condition than at ambient laboratory conditions. The dissipation rate followed a first-order kinetic model with the DT5o value at 36-46 days and DT90 around 119-152 days. It is interesting to note that paraquat dissipation in the tropical soil conditions as found from this study was faster than in the temperate region with half-life than 100 days. Potential risk of paraquat to environment and ecosystems interpreted from its behaviors indicated that the potential of paraquat exposure could be expected in surface water by the movement of strong adsorbed paraquat with eroded soil. The potential exposure in groundwater, soil organisms and human are nil because of the low mobility and less desorption capacity.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Paraquat
Geographic subdivision Thailand
-- Yom River Basin
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Soils
General subdivision Environmental aspects
-- Thailand
Geographic subdivision Yom River Basin
700 0# - ADDED ENTRY--PERSONAL NAME
Personal name Preeda Pakpian,
Relator term Chairperson
700 0# - ADDED ENTRY--PERSONAL NAME
Personal name Chongrak Polprasert,
Relator term Examination Committee
700 0# - ADDED ENTRY--PERSONAL NAME
Personal name Yuwaree In-na,
Relator term Examination committee
700 0# - ADDED ENTRY--PERSONAL NAME
Personal name Samorn Muttamara,
Relator term Examination Committee
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Khan, Shahamat U.,
Relator term Examination committee
710 2# - ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Naresuan University,
Relator term Scholarship donor
710 2# - ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Asian Institute of Technology Fellowship,
Relator term Scholarship donor
810 2# - SERIES ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Asian Institute of Technology.
Title of a work Dissertation ;
Volume/sequential designation no. EV-05-1
856 ## - ELECTRONIC LOCATION AND ACCESS
Materials specified Full-Text
Uniform Resource Identifier <a href="http://203.159.5.9/ait-thesis/detail.php?q=B09376">http://203.159.5.9/ait-thesis/detail.php?q=B09376</a>
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a 240401
998 ## - LOCAL CONTROL INFORMATION (RLIN)
Operator's initials, OID (RLIN) 0
Cataloger's initials, CIN (RLIN) 060702
First date, FD (RLIN) m
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l mnait
945 ## - LOCAL PROCESSING INFORMATION (OCLC)
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942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type 22-AIT Thesis (Replacement)
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type 40-Archives
909 ## - LOCAL ITEMS USED
Barcode Barcode : 30050120725956
CREATED CREATED : 2012-08-16
RECORD Id RECORD # : i12687613
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Barcode Barcode : 30050160004510
CREATED CREATED : 2016-02-02
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      Available for Loans Asian Institute of Technology Library Asian Institute of Technology Library AIT Publications 18/08/2026   AIT Diss. no.EV-05-1 30050120725956 18/08/2026 3 18/08/2026 22-AIT Thesis (Replacement)
      Available for Loans Asian Institute of Technology Library Asian Institute of Technology Library Archives 18/08/2026   AIT Diss. no.EV-05-1 30050160004510 18/08/2026   18/08/2026 40-Archives
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